Round One
William Munny (Unforgiven) vs. Xander Cage (xXx)
Harry Callahan (Dirty Harry) vs. Conan (Conan the Barbarian)
Seth Gecko (Dusk Till Dawn) vs. The Man With No Name (A Fistful of Dollars)
Casey Ryback (Under Siege) vs. Martin Riggs (Lethal Weapon)
Indiana Jones (Indiana Jones) vs. Marv (Sin City)
John Rambo (Rambo) vs. Alice (Resident Evil)
Ben Richards (The Running Man) vs. Frank Dux (Bloodsport)
The Boondock Saints (The Boondock Saints) vs. Hans Solo (Star Wars)
William Wallace (Braveheart) vs. Batman (Batman)
Obi Wan Kenobi (Star Wars) vs. JT McQuade (Lone Wolf McQuade)
Dirk Pitt (Sahara) vs. The Bride (Kill Bill)
The Phantom (The Phantom) vs. John McClane (Die Hard)
Neo (The Matrix) vs. Robin Hood (Robin Hood: Prince of Thieves)
Dutch Mantell (Predator) vs. Vince Vega (Pulp Fiction)
Sam Spade (The Maltese Falcon) vs. Spiderman (Spiderman)
Jack Carter (Get Carter) vs. El Mariachi (Desperado)
Jack T. Colton (Romancing the Stone) vs. Jason Bourne (The Bourne Identity)
James Bond (Goldeneye) vs. The Crow (The Crow)
Nameless (Hero) vs. Leon (The Professional)
Jack Traven (Speed) vs. Van Helsing (Van Helsing)
Charlie's Angels (Charlie's Angels) vs. Ripley (Alien)
Maximus (Gladiator) vs. Tom Cody (Streets of Fire)
Connor McLeod (Highlander) vs. Buffy (Buffy the Vampire Slayer)
Wong Fei-hung (Legend of Drunken Master) vs. Ethan Hunt (MI:2)
Axel Foley (Beverly Hills Cop) vs. Beck (Welcome to the Jungle)
Aragorn (Lord of the Rings) vs. Corben Dallis (The Fifth Element)
Ash (Evil Dead) vs. Paul Kersey (Deathwish)
Mad Max (Mad Max) vs. John Matrix (Commando)
Marion Cobretti (Cobra) vs. Dwight (Sin City)
The Punisher (The Punisher) vs. The Terminator (The Terminator)
Riddick (Pitch Black) vs. Rick O'Connell (The Mummy)
Wolverine (X-Men) vs. Blade (Blade Trinity)
Zoro (Zoro) vs. Selene (Underworld)
Daredevil (Daredevil) vs. Catwoman (Catwoman)
Superman (Superman) vs. The Scorpion King (The Scorpion King)
Agent K (Men in Black) vs. Elektra (Elektra)
Hellboy (Hellboy) vs. John Spartan (Demolition Man)
I can't believe that I picked Catwoman to go onto round two. The fact that she is more effective than Daredevil is a worry for Ben Affleck's manhood.
There are some other low standard match-ups, like the Sam Spade (The Maltese Falcon) vs. Spiderman (Spiderman) and the Zoro (Zoro) vs. Selene (Underworld) mastchups.
On the other side of the coin, the battle between Mad Max (Mad Max) vs. John Matrix (Commando) is like choosing one of your kids not to face certain death. Matrix would only need one toe to beat up Daredevil.
Btw, anyone who picks Alice over John Rambo is braindead. Rambo is one vicious sob.